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Q.

Assertion (A): N-  alkyl benzene sulphonamide is soluble in alkali. 

Reason (R): The hydrogen attached to nitrogen in sulphonamide is strongly acidic due to the presence of a strong electron withdrawing sulfonyl group.

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a

 Both (A) and (R) are true and (R) is the correct explanation of (A)

b

 (A) is true but (R) is false

c

 Both (A) and (R) are false

d

 Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

 

 

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due to the presence of a strong electron-withdrawing group the hydrogen atom attached to nitrogen is very acidic in nature,

Due to this acidic hydrogen, N-  alkyl benzene sulphonamide is soluble in alkali.

Thus, both assertion and reason are true and the reason is the correct explanation of assertion.

Hence, option (A) is correct.

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