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Q.

Assertion: Chloride is confirmed by chromyl chloride test
Reason: Chlorine is evolved when chloride is heated with con. H2SO4

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a

Both A and R are correct and R is the correct explanation of A

b

Both A and R are correct but R is not the correct explanation of A

c

A is true, but R is false

d

A is false, but R is true

answer is C.

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Detailed Solution

Chloride liberates deep red vapours of chromyl chloride (CrO2Cl2) when heated with solid K2Cr2O7 and con.H2SO4

K2Cr2O7+4NaCl+6H2SO4  2CrO2Cl2+2KHSO4+4NaHSO4

But Chlorine is not evolved when chloride is treated with conc.H2SO4.

2NaCl +H2SO42HCl +Na2SO4

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