Q.

Assertion: In Hofmann bromamide reaction, the amine formed has one carbon atom less than the parent 1° amide.
Reason: N-methyl acetamide undergoes Hofmann bromamide reaction.
Select the most appropriate answer from the options given below:

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a

Both A and R are true and R is the correct explanation of A.

b

Both A and R are true but R is not the correct explanation of A.

c

A is false but R is true.

d

A is true but R is false.

answer is C.

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Detailed Solution

Only primary amines can be prepared from amides RCONH2 by treating with Br2 and KOH. N-methyl acetamide CH3CONHCH3 is a secondary amide. Thus, it does not undergo Hofmann bromamide reaction.

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