Q.

Assertion: K4[Fe(CN)6] Fe3++CO2+NO3 ; equivalent weight of  K4[Fe(CN)6]=M61

(M=molecular weight)
Reason: K4[Fe(CN)6] Fe3++CO2+NO3; n-factor for  K4[Fe(CN)6]  is 61

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a

Assertion is false & Reason is true

b

Assertion is true & Reason is false

c

Both Assertion & Reason are correct , Reason is not the correct explanation of Assertion

d

Both Assertion & Reason are correct , Reason is the correct explanation of Assertion

answer is A.

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Detailed Solution

Fe+2 Fe+3+e,nf=1 6CN CO2 x3=1                x4=0                    nf=6×2=12 x=+2                      x=+4 6(N3) NO3     (3)                          (+5)                          nf=6×8=48nf=1+12+48=61       

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