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Q.

Assertion : Lucas reagent is a mixture of anhydrous ZnCl2. and concentrated HCl. 

Reason : Primary alcohol produce ppt. with Lucas reagents.  

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a

If both assertion and reason are true and the reason is the correct explanation of the assertion.

b

If both assertion and reason are true but reason is not the correct explanation of the assertion.

c

If assertion is true but reason is false. 

d

If the assertion and reason both are false. 

answer is C.

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Detailed Solution

Lucas reagent is a mixture of anhydrous ZnCl2 and concentrated HCI. This reagent is used for the distinction of monohydric alcohols and the test is called Lucas test.

  • Tertiary alcohols produce a precipitate immediately after the addition of Lucas reagent.
  • Secondary alcohols produce precipitate after 5 minutes
  • Primary alcohols do not produce any precipitate
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