Q.

Assertion : Melting of ice is spontaneous above 273K. 
Reason : Above 273K, for the process of melting of ice, magnitude of  ΔH>TΔS

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a

(A) is true but (R) is false

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

d

Both (A) and (R) are false

answer is C.

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Detailed Solution

  ΔH&ΔS  are positive for melting of ice.Teq=273K;
 
Above 273 K,  ΔG=Ve;

Ve=+Ve273+VeorΔG=ΔHTΔS

The above relation becomes correct only when the magnitude of  ΔΗ<TΔS

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