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Q.

Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with Br2 in carbon disulphide at 273K.
Reason: Bromine is highly polarised in carbon disulphide.

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a

Assertion and Reason are correct and Reason is the correct explanation of Assertion

b

Assertion and Reason both are incorrect

c

Assertion is correct and Reason is incorrect

d

Assertion And Reason are correct but reason is not the correct explanation of Assertion

answer is B.

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Detailed Solution

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CS2 is non-polar solvent cannot polarize 

Phenol with (bromine + water) can give 2,4,6-Tribromophenol 

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Assertion: Phenol forms 2, 4, 6 – tribromophenol on treatment with Br2 in carbon disulphide at 273K.Reason: Bromine is highly polarised in carbon disulphide.