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Q.

Assertion: SN2 reaction of an optically active aryl halide with an aqueous solution of KOH always gives an alcohol with opposite sign of rotation

ReasonSN2 reaction always proceed with retention of configuration

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a

If both the Assertion and Reason are incorrect.

b

If both Assertion and Reason are correct, but Reason is not the correct explanation of Assertion.

c

If both Assertion and Reason are correct and the Reason is the correct explanation of Assertion.

d

If Assertion is correct but Reason is incorrect.

answer is D.

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Detailed Solution

Ans. (d): Assertion is False, because aryl halide do not undergo nucleophilic substitution under ordinary condition this is due to resonance, because of which the carbon-chlorine bond acquires partial double bond character, hence it becomes shorter and stronger and thus cannot be replace by nucleophiles. 

Also, reason is false SN2 reaction product with inversion of configuration.

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