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Q.

Assertion: Sulphur exist as S8 but oxygen exists as O2.
Reason: Oxygen forms pπpπ multiple bond due to small size and small bond length but pπpπ bonding is not possible in sulphur.

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a

Assertion is correct, but reason is wrong statement. 

b

Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion

c

Both assertion and reason are correct statements, and reason is the correct explanation of the assertion

d

Assertion is wrong but reason is correct statement

answer is A.

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Assertion: Sulphur exist as S8 but oxygen exists as O2.Reason: Oxygen forms pπ−pπ multiple bond due to small size and small bond length but pπ−pπ bonding is not possible in sulphur.