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Q.

Assertion(A) : During E2  elimination of ethylidene bromide to form Ethyne; NaNH2 is a better dehydrohalogenating agent than alcoholic KOH  .
Reason (R) : OH  is more basic than NH2 .  

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a

A is correct and R is wrong 

b

A & R are correct but R is not correct explanation to A

c

A & R are correct but R is correct explanation to A.

d

A is wrong and R is correct 

answer is C.

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Detailed Solution

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NaNH2 is a stronger base than KOH. Intermediate vinyl Bromide needs stronger Base; NaNH2 for better yield.  

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Assertion(A) : During E2  elimination of ethylidene bromide to form Ethyne; NaNH2 is a better dehydrohalogenating agent than alcoholic KOH  .Reason (R) : OH−  is more basic than NH2− .