Q.

Assertion(A) : Solubility of BaSO4  in  0.1MNa2SO4 is 109M  hence it KSP  is  1018
Reason(R) : In Aqueous solution, solubility product of BaSO4   = S2  (Where S is a solubility of BaSO4 ) 
 

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a

Both A and R are but R is not the correct explanation of A

b

Both A and R are true and R is the correct explanation of A

c

A is false but R is true

d

A is true but R is false

answer is D.

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Detailed Solution

BaSO4 Ba2++SO42   S=109KSP=109×0.1     (0.1+1090.1)                        S           (S+0.1)   KSP=[Ba+2][So42]     KSP=109×(0.1+109)   KSP=1010

Ans  KSP(BaSO4)=S2  (in aqueous solution)

 

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