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Q.

Assuming complete dissociation, which of the following aqueous solutions will have the same pH value.

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a

100ml of 0.01MHCl

b

Mixture of 50ml of 0.02MH2SO4 and 50ml 0.02MNaOH

c

100ml of 0.01MH2SO4

d

50ml of 0.01MHCl

answer is A, D.

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Detailed Solution

 M.eq. of 0.01MHCl=0.01×1001000=1×103 pH=3

 M.eq. of 0.02MH2SO4=0.04×501000=2×103 0.02MNaOH=0.02×501000=1×103  Left H+=2×1031×103=1×103pH=3

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