Q.

Assuming complete ionization, same moles of which of the following compounds will require the least amount of acidified KMnO4 for complete oxidation

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a

FeNO22

b

FeSO4

c

FeSO3

d

FeC2O4

answer is A.

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Detailed Solution

For complete ionization, one mole of FeSO4 requires 0.5 moles of K2Cr2O7 and one mole of FeSO3 requires 0.6 moles of K2Cr2O7. One mole of FeC2O4 required 0.6 moles of K2Cr2O7. One mole of Fe(NO2)2 required 1 mole of K2Cr2O7.

Therefore, FeSO4 requires least amount of moles of K2Cr2O7.

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