Q.

Assuming ideal behavior, the magnitude of log K for the following reaction at 250Cx×101. The value of x is ___________ (Integer answer)

3HCCH(g)C6H6(l)

[Given: (equivCH)  = 2.04×105Jmol1;

ΔrG0C6H6 = 1.24×105Jmol1;

R = 8.314 JK1mol1]

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answer is 1.

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Detailed Solution

 ΔrG0 = -RTlnKeq

ΔreactionG0 = ΔGF0(Product)-ΔGF0(Reactant)

-RTlnKeq = [1× (1.24×105)]  - [3×(2.04×105)]

-RTlnKeq = [1.24×105)] – [-6.12×105)]

-RTlnKeq = 4.88×105

-log K = 4.88×1052.303×8.314×298

log K = -85.526 = -8.5×10-1.

Hence, the answer is -8.5×10-1.

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