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Q.

Assuming ideal behaviors, the magnitude of log K for the following reaction at 25oC is
-x x 10-1. The Value of x is _____. (Integer answer)
3HCCH(g) C6H6(l)
[Given: fGo (HCCH) = -2.04 x 105 J mol-1 ;
fGo (C6H6) = -1.24 x 105 J mol-1 ; R=8.314 K-1 mol-1]

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answer is 855.

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Detailed Solution

3HCH(g)C6H6(l)ΔGo=RTInK=2.303RTlogK Given, ΔGfOC6H6=1.24×105Jmol1 ΔGfO(CHCH)=2.04×105Jmol1ΔGr=ΔGfC6H63ΔGfC2H2ΔGr=1.24×1053×2.04×105ΔGr=4.88×105Jmol1
So, 4.88 x 105 = -2.303 x 8.314 x 298 logK
logK=4.88×1055705.848=85.52=855×101
X=855

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