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Q.

At 0°C ice and water are in equilibrium and G and S  for the conversion of ice to liquid water is:

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a

-ve, zero

b

 +ve, 21.98 J K-1 mol-1

c

0, 21.98 J K-1 mol-1

d

zero, zero

answer is A.

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Detailed Solution

Since the given process is in equilibrium i.e., 

ΔG=0ΔG=ΔH-TΔS

or

O=ΔH-TΔS ΔH=TΔS ΔS=ΔHT

Substituting the values:

S=6273×103 J K-1 mol-1      =21.98 J K-1 mol-1

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At 0°C ice and water are in equilibrium and ∆G and ∆S  for the conversion of ice to liquid water is: