Q.

At 1000 K, solid carbon, CaO and CaCO3 are mixed and allowed to attain following equilibrium :

CaCO3(s)CaO(s)+CO2(g); Kp=4×102atm

C(s)+CO2(g)2CO(g); Kp=2atm

What is the pressure of CO at equilibrium (in atm)?

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a

25atm

b

0.04 atm

c

52

d

50 atm

answer is D.

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Detailed Solution

In the following reaction we have,

CaCO3CaO(s)+CO2(g)Px

C(s)+CO2(g)2CO(g)Px2x

PCO2KP1=KP2PCO=2210

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