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Q.

At 25°C and I atm pressure, the enthalpies of combustion are as given below:

Substance

H2

C graphite

C2H6g

ΔCH0KJmol1

-286.0

-394.0

-1560.0

 The enthalpy of formation of ethane is 

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a

+54.0kJmol1

b

68.0kJmol1

c

86.0kJmol1

d

+97.0kJmol1

answer is C.

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Detailed Solution

Given, H2g+12O2gH2Ol

ΔH°=286.0KJ/mol

Cgraphite+O2gCO2g;ΔH°=394.0KJmol

C2H6g+72O2g2CO2g+3H2Ol

ΔH°=1560.0KJ/mol

Enthalpy of formation of C2H6g  can be written as 2Cgraphite+3H2gC2H6g

So, by doing   3i+2iiiii  we can get desired relation

ΔHf°C2H6=3x286+2x3941560

=86.0kJmol1

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At 25°C and I atm pressure, the enthalpies of combustion are as given below:SubstanceH2C graphiteC2H6gΔCH0KJmol−1-286.0-394.0-1560.0 The enthalpy of formation of ethane is