Q.

At 25°C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54ohm1cm2mol1 and at infinite dilution its molar conductance is 238ohm1cm2mol1  The degree of ionisation of ammonium hydroxide at the same concentration and temperature is

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a

4.008%

b

40.800%

c

2.080%

d

20.800%

answer is C.

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Detailed Solution

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Degree of dissociation, α=ΛmcΛm
where Λmc= molar conductivity at given concentration
Λm = molar conductivity at infi nite dilution
α=9.54238=0,04008=4.008%

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