Q.

At 25° C, the dissociation constant of a weak monoprotic acid HAKa is numerically equal to the dissociation constant of its conjugate base A (Kb) Which of the following statement(s) is are correct?

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a

The pH of 0.1 M aqueous solution of the conjugate base A is 10.0.

b

The pH of 0.1 M aqueous solution of the acid, HA, is 4.0.

c

The pH of an aqueous solution containing 0.1 M -HA and 0.01  M-HCl is 2.0.

d

The dissociation constant of the acid, HA, is 107 at 25C

answer is A, B, C, D.

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Detailed Solution

(a) Ka×Kb=Kw(always)

If Ka=KbKa=107

(b) pH=12[7log0.1]=4.0

(c) pOH=12[7log0.1]=4.0

(d) H+Total =H+HCl=0.01

So, pH=2

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