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Q.

At 250C, the ionic mobility of CH3COO,  H+  are respectively  4.1×104,  3.63×103 cm/sec. The conductivity of 0.001 M   CH3COOH  is 5×105S.cm1 . Dissociation constant of   CH3COOH

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a

3×106

b

3×104

c

1.64×105

d

3×105

answer is A.

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Detailed Solution

α=MM0=

M=1000×5×105103

=1000×5×105×103

50Ω1cm2mol1

M0=965004.1×104+3.63×103

=386

α=50386=0.129

α=kac

0.1292=ka106

ka=1.64×105

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