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Q.

At  25C  o the KSP values of  Ni (OH)2  and Cd(OH)2 are  2.0×1015 and  2.5×1014 respectively. If S1 and S2 are respectively their molar solubilities, then the ratio of S1 to S2 is

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a

3 : 8

b

4 : 3

c

25 : 2

d

2 : 25

answer is D.

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Detailed Solution

4s13=2×10-15

s13=5×10-16

4s23=2.5×10-14

s23=62.5×10-16

s1s23=5×10-1662.5×10-16=0.08

s1s2=5×10-1662.5×10-1613=0.08

s1s2=8100=225

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