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Q.

At 27°C the reaction, C6H6(l)+15/2O2(g)6CO2(g)+3H2O(l)

proceeds spontaneously because the magnitude of   

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a

ΔH = TΔS

b

ΔH > TΔS

c

ΔH < TΔS    

d

ΔH > 0 and TΔS< 0

answer is B.

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Detailed Solution

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For the given reaction,

ΔS = negative  (∵ Lesser number of gaseous products are formed)

 –TΔS = positive

But ΔH = –ve

Since, it is a combustion reaction and hence exothermic.

ΔG = ΔH – TΔS ; So for ΔG to be negative, |ΔH>TΔS|

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