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Q.

At 283 K a saturated solution of solid X can be prepared by dissolving 21.0 g of it in 100 g of water. The maximum amount of X which can be dissolved in 100 g of water at 313 K is 62.0 g. An attempt is made to dissolve 50.0 g of X in 100 g of water at 313 K.

Which of the above statements are correct ?

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a

Solubility of X decreases with increases of temperature

b

At 313 K 29.0 g of X will remain un dissolved

c

On cooling the solution of X from 313 K to 283 K less than 29.0 g of X will crystallize out

d

All the 50.0 g of X will dissolve at 313 K

answer is A.

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Detailed Solution

We know that solubility depends on temperature

  Generally when temperature increases, solubility also increases.

  By decreasing the temperature of the solution it acts as super saturated solution and solubility decreases.

Hence 50.0g of X will easily dissolve in 313K as the maximum amount mentioned is 62g.

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