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Q.

At  298 K 
 N2(g)+3H2(g)2NH3(g),K1=4×105 N2(g)+O2(g)2NO(g),K2=1.6×1012 H2(g)+12O2(g)H2O(g),K3=1.0×1013
 Based on above equilibria, the equilibrium constant of the reaction,
 2NH3(g)+52O2(g)2NO(g)=1.0×1013
 Is _______________ ×1033 (Nearest integer)
 

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a

8

b

1

c

6

d

4

answer is A.

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Detailed Solution

N2(g)+3H2(g)2NH3(g),K1=4×105       ...........(i) N2(g)+O2(g)2NO(g),K2=1.6×1012       .........(ii) H2(g)+12O2(g)H2O(g),K3=1.0×1013       ..........(iii)

By applying  (ii)+3×(iii)(i),weget

2NH3(g)+52O2(g)2NO(g)+3H2O(g) keq=k2×k33k1=1.6×1012×(1013)34×105 =1.64×1032=4×1033

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