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Q.

At 298 K, the Ksp value of Fe(OH)3 in aqueous solution is 3.8×10-38. The solubility of Fe3+ions will increase when.

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a

Saturated solution is exposed to sun light

b

pH is increased 

c

pH is 7

d

pH is decreased

answer is C.

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Detailed Solution

According to La-Chatelier principle.

Fe (OH)3 Fe+3  +3OH-

H++OH-H2O

According to the given equation as OH- concentration decreases reaction proceeds forward so Fe3+ concentration increases and the solubility increases.
Hence the right answer is(C) pH is decreased.

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