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Q.

At 298K, the molar equilibrium concentrations of Ag+, NH3 and [Ag(NH3)2]+ for the equilibrium  Ag+(aq) + 2NH3(aq) [Ag(NH3)2]+(aq) were found to be 10-1, 10-3, and 10-1 respectively. The value Kc is

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a

106

b

10-6

c

5×104

d

2×10-3

answer is A.

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Detailed Solution

KcAgNH32+Ag+NH32

=10-110-1×10-6=106

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At 298K, the molar equilibrium concentrations of Ag+, NH3 and [Ag(NH3)2]+ for the equilibrium  Ag+(aq) + 2NH3(aq) ⇌[Ag(NH3)2]+(aq) were found to be 10-1, 10-3, and 10-1 respectively. The value Kc is