Q.

At 298K, the standard electrode potentials of Cu2+/Cu,Zn2+/Zn,Fe2+/Fe and Ag+/Ag are 0.34 V, -0.76 V, -0.44 V and 0.80 V, respectively.
On the basis of standard electrode potential predict Which of the following reaction can not occur?

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a

CuSO4(aq)+Fe(s)FeSO4(aq)+Cu(s)

b

CuSO4(aq)+Zn(s)ZnSO4(aq)+Cu(s)

c

2CuSO4(aq)+2Ag(s)2Cu(s)+Ag2SO4(aq)

d

FeSO4(aq)+Zn(s)ZnSO4(aq)+Fe(s)

answer is C.

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Detailed Solution

‘Ag’ has high S.R.P, So it oxidises by ‘Cu’ but not reduced.

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