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Q.

At 300 K, the conductivity of 0.01 mol dm-3 aqueous solution of acetic acid is 19.5×105mhocm1 and limiting molar conductivity of acetic acid at the same temperature is 390mhocm2mol1. The degree of dissociation of acetic acid is

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a

5.0×102

b

5.0×105

c

2.5×105

d

7.5×102

answer is B.

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Detailed Solution

Concentration (C) = 0.01 mol dm−3 = 10 mol m−3.

Conductivity (K) = 19.5 × 10−5 S cm−1 = 19.5 × 10−3 S m−1

Limiting molar conductivity(∧m) = 390 S cm2 mol−1 = 390×10−4 S m2 mol−1
Molar Conductivity (m)=KC=19.5×103 S m110 mol m3=19.5×104 S m2 mol1

The degree of dissociation is determined as:

Degree of dissociation (α)=mm0=19.5×104 S m2 mol1390×104 S m2 mol1=0.05=5.0×10-2

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