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Q.

At 300 K, the entropy change for the reaction given below is

2H2(g)+O2(g)  2H2O(l)

Standard entropies of H2(g), O2(g)  and H2O(l) are 126.6, 201.20 and 68.0 J K-1 mol-1 respectively.

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a

-318.4 J K-1 mol-1

b

+318.4  J K-1 mol-1

c

+31.84  J K-1 mol-1

d

-159.2 J K-1 mol-1

answer is A.

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Detailed Solution

SReaction=Sproduct-Sreactant                =2 × SH2O- 2 × SH2 + SO2               =2 × 68- 2 × 126.6 + 201.20=-318.4 JK-1 mol-1

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