Q.

At 300K rate constant for A product at t = 50 min is 0.02 s-1, then rate constant at
t = 75 min & 310 k will be ( in s-1)

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a

0.0425

b

0.0225

c

0.04

d

0.04× 25

answer is C.

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Detailed Solution

At t=50sec , 300K ; K = 0.02 sec-1

t= 75sec , 310K ; K =?

 With time rate constant does not change but rate constant change with temperature

K increases 2times with raise 100C

300K K =0.02 sec-1

310 K K =2×0.02 sec-1=0.04 sec-1

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