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Q.

At 623K and at 10 atm Kp for N2+3H22NH3 is 7 x 10-4. At a certain instant,the partial pressures of N2,H2 and NH3 in the reaction mixture are respectively 2.5 atm,3 atm and 4.5 atm respectively. Correct statement at equilibrium is that

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a

partial pressure of N2 = 2.5 atm

b

Partial pressure of NH3 > 4.5 atm

c

partial pressure of H2 < 3 atm

d

Partial pressure of N2 > 2.5 atm

answer is C.

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Detailed Solution

QppNH32pN2×pH23=(4.5 atm)22.5 atm×(3 atm)3= 0.3 atm-2 

Qp > Kp reaction must move to left to reach equilibrium. At equilibrium partial pressures of N2 and H2 must be higher and partial pressure of NH3 must be lower than the given values.

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