Q.

At a certain temperature, the value of the slope of the plot of osmotic pressure (π) against concentration (C in mol L1) of a certain polymer solution is 291 R.  The temperature at which osmotic pressure is measured, is (R is gas constant)

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a

18 K

b

564 K

c

2710C

d

180C

answer is B.

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Detailed Solution

A plot of osmotic pressure vs concentration will be linear with slope = RT

as π=CRT

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So, RT=291R

T=291K=(291273)0C=180C

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