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Q.

At a given temperature, total vapour pressure in Torr of a mixture of volatile components A and B is given by P=12075xB, hence vapour pressure of pure components A and B respectively (in Torr) are -

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a

120, 195

b

120, 75

c

120, 45

d

75, 45

answer is C.

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Detailed Solution

PS=PAoxA+PBoxB

=PAo1xB+PBoxB

PS=PAo+xBPBoPAo......1

Given equation, PS=12075xB......2

On comparing eq. (1) & (2), we get

PAo=120,PBoPAo=75

PBo120=75

PBo=45.

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At a given temperature, total vapour pressure in Torr of a mixture of volatile components A and B is given by P=120−75xB, hence vapour pressure of pure components A and B respectively (in Torr) are -