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Q.

At certain temperature a solution 3 moles of liquid A(p0 = 500 torr) and 1 mol of liquid B(p0 = 340 torr) has a vapour pressure of 435 torr, we can conclude that

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a

a solution of 50 mL of A and 50 mL of B must have a volume of 100 mL.

b

the solution shows negative deviation from Raoult’s law

c

on mixing the two liquids heat must be given out so as to obtain solution at the same temperature

d

entropy of mixing is zero.

answer is B, C.

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Detailed Solution

P=PA0xA+PB0xB=460 (cal. pressure), but actual pressure = 435, So, it is –ve deviation.
ΔH=ve.

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