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Q.

At constant temperature 80% AB dissociates into  A2 and B2 , then the equilibrium constant for 2ABgA2g+B2g  is

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a

1

b

0.25

c

16

d

4

answer is D.

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Detailed Solution

2AB(g)A2(g)+B2(g) Let nAB=100

Percentage of decompositions of AB = 80

2 moles of AB decomposes 1 mole of A2 and 40 moles of B2

Stoichiometry

2 mole

2AB(g)

 

 

1 moleA2(g)

1 mole

B2(g)

 

 

Initial moles

1

0

0

Moles at equilibrium

(100-80)

40

40

 Equilibrium concentration 20V 40VKC=A2B2[AB]240V  KC=40V40V20V2KC=40×4020×20KC=4 

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