Q.

At constant temperature, the equilibrium constant Kp for the decomposition reaction N2O42NO2 is expressed by, 

Kp=4x2P1-x2 where, P=pressure, x=extent of decomposition. Which of the following statements is true?

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a

Kp remains constant with change in p and x decreases with pressure

b

Kp increases with increase of x

c

Kp increases with decrease of x

d

Kp increases with increase of P

answer is D.

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Detailed Solution

Kp is a characteristic constant for a given reaction and changes only with temperature

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At constant temperature, the equilibrium constant Kp for the decomposition reaction N2O4⇌2NO2 is expressed by, Kp=4x2P1-x2 where, P=pressure, x=extent of decomposition. Which of the following statements is true?