Q.

At high pressure the following reaction is zero order. 2NH3(g)1130K Platinum catalyst N2(g)+3H2(g)
Which of the following options are correct for this reaction?

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a

Rate of reaction = Rate constant

b

Rate of the reaction depends on concentration of ammonia.

c

Further increase in pressure will change the rate of reaction.

d

Rate of decomposition of ammonia will remain constant until ammonia disappears completely. 

answer is A, C, D.

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Detailed Solution

Given, chemical reaction is 2NH3(g)1130K Platinum catalyst N2(g)+3H2(g)
At very high pressure reaction become independent of concentration of ammonia, i.e. zero order reaction.
Hence, Rate =kpNH30 Rate =k
(a) Rate of reaction = Rate constant
(c) Rate of decomposition of ammonia will remain constant until ammonia disappears completely.
(d) Since, formation of ammonia is a reversible process further increase in pressure will change the rate of reaction. According to Le-Chatelier principle increase in pressure will      favour in backward reaction.

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