Q.

At infinite dilution, molar conductivity of Ba2+ and Cl-ions are =127.32 S cm2/mol and 76.34S cm2/mol respectively. What is  m for Bacl2 at same dilution ?

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a

330.98 S cm2/mol-1

b

90.98 S cm2/mol-1

c

280 S cm2/mol-1

d

203.6 S cm2/mol-1

answer is A.

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Detailed Solution

Here given is :
Molar conductivity of Ba2+=127.32 s cm2/mol-1
Molar conductivity ofCl-=76.34 S cm2/mol-1
Following is reaction 

BaCl2Ba2++2Cl-
According to Kohlrausch's law,

m,BaCl2=m,Ba2++2×m,Cl-
By putting given values in equation,

m,Bacl2=127.32+2×76.34=280 S cm2/mol-

Therefore option A is right.

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