Q.

 At same temperature N2O4 is dissociated to 40% and 50% at total pressure P1and P2 atm respectively in NO2 

 

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a

7/4

b

none of these 

c

4/7

d

4/5

answer is B.

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Detailed Solution

As temperature is constant,

KP1=KP2α121α12×P1=α221α22×P2P1P2=0.250.75×0.840.16=74

Then the ratio of P1 and P2 is: 7 : 4.

Hence, the correct option is b.

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