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Q.

At T(k) 100 litres of dry oxygen is present in a sealed container. It is subjected to silent electric discharge,till the volumes of oxygen and ozone become equal .What is the volume(in litres) of ozone formed at T(k)?

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a

50

b

60

c

30

d

40

answer is D.

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Detailed Solution

$3 O_{2} ⇄ 2 O_{3}$
Volume of oxygen converted into ozone $= X l i t$
Volume of ozone formed $= \frac{2 x}{3} l i t$
Volume of oxygen left behind $= (100 - x) l i t$
$\begin{aligned} \frac{2 x}{3} = 100 - x \\ 2 x = 300 - 3 x \\ 3 x + 2 x = 300 \\ x = 60 lit \end{aligned}$
Volume of $O_{3}$ formed $= \frac{60 \times 2}{3} = 40 l i t$

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