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Q.

At T(K), equal weights of H2, D2, and T2 are present in closed vessel. The pressure exerted by this gaseous mixture is P atm. The ratio of partial pressures of T2, D2 and H2 is approximately
(H, D and T are isotopes of hydrogen).

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a

0.18:0.27:0.54

b

0.33:0.33:0.33

c

0.54: 0.27: 0.18

d

0.25:0.50:0.25

answer is B.

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Detailed Solution

ptotal=pH2+pD2+pT2 pH2=mole fraction of H2×ptotal mole fraction of H2=number of moles of H2total number of moles pT2:pD2:pH2 mole fraction of T2×ptotal:mole fraction of D2×ptotal:mole fraction of H2×ptotal

Now weights are same for three gases:

1616+14+12:1416+14+12:1216+14+12 0.16:0.25:0.5

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