Q.

At temperature T, a compound AB2(g) dissociates according to the reaction 2AB2(g)2AB(g)+B2(g)with a degree of dissociation ‘x’ which is small as compared to unity. The expression for KP,in terms of ‘x’ and total pressure ‘P’ is

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a

px33

b

Px32

c

px22

d

px23

answer is A.

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Detailed Solution

2AB2(g)2AB(g)+B2(g)

Initial : P            O            O

At equli: p-xp       px       xp2 

Kp=PAB.PB2   2PAB2

=(p2)2xP2(p-xp)2

KP=P2x2.X.P2×1P2=px22

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