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Q.

At   the molar conductances at infinite dilution for the strong electrolytes NaOH,NaCl and BaCl2 are 248×104126×104 and 280×104S.m2mol1 respectively λm0.  Ba(OH)2 in S.m2mol1 is  

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a

52.4×104

b

524×104

c

402×104

d

262×104

answer is B.

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Detailed Solution

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Molar conductance of  Ba(OH)2=molar conductance of BaCl2 + (2  molar conductance of  ) NaOH– (2  molar conductance of  NaCl)
=[280+(2×248)(2×126)]×104Sm2mol1 =524×104Sm2mol1

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