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Q.

At 20°C the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The mole fraction of benzene in the vapour phase at 20°C above equimolar mixture of benzene and methyl benzene is  _______×10-2

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answer is 78.

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Detailed Solution

PTotal =XBPB+XMBPMB

XMB represents benzene's mole fraction in the solution phase

XMB represents methyl benzene's mole fraction in the solution phase

YBPT otal =XBPB

YB represents the vapor phase mole fraction of benzene 

YB=0.5×700.5×70+0.5×20¯=0.7777

YB=77.77×10-2

YB=78×10-2


x=78

Hence, the correct answer is 78.

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