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Q.

At 298 K, the molar equilibrium concentrations of Ag+,NH3 and AgNH32+for the equilibrium Ag(aq)++2NH3(aq)AgNH33(aq)+ were found to be 10-1,10-3, and 10-1 respectively. The value Kc is

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a

2×10-3

b

5×104

c

106

d

10-6

answer is B.

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Detailed Solution

It is given to find the value Kc. At 298 K, the molar equilibrium concentrations of Ag+,NH3 and AgNH32+for the equilibrium were found to be 10-1,10-3, and 10-1 respectively.

Ag(aq)++2NH3(aq)AgNH33(aq)+

 KcAggNH32+Ag+NH32  = 10-110-11032  = 10-110-1106  = 10-6 

Hence the correct option is (B) 10-6.

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