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Q.

At 35°C, the vapour pressure of CS2 is 512 mmHg ·and that of acetone is 344 mm Hg. A solution of CS2 in acetone has a total vapour pressure of 600 mm Hg

The false statement amongst the following is

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a

CS2 and acetone are less attracted to each other than to themselves

b

 Heat must be absorbed in order to produce the solution at 35°C

c

 Raoult's law is not obeyed by this system

d

 A mixture of 100mL CS2 and 100mL acetone has a volume<200mL

answer is C.

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Detailed Solution

The vapour pressure of mixture ( =600 mm Hg) is greater than the individual vapour pressure of its constituents

(Vapour pressure of CS2=512mmHg, acetone =344mmHg) Hence, the solution formed shows positive deviation from Raoult's law.

 (a) ΔSol H>0 (b) Raoult's law is not obeyed

 (c) Δsol  Volume >0

 (d) CS2 and Acetone are less attracted to each other than to themselves.

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