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Q.

Atomicity of dimeric phosphorous pentoxide is ‘x’ and the number of shared electron pairs is ‘y’. Then
a) y – x = 6            b) 2x = y + 8           c) 10x – 7y = 0

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a

Only ‘c’ is correct

b

All the above are correct

c

Only ‘a’ is correct

d

Only ‘b’ is correct

answer is D.

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Detailed Solution

Dimer of phosphorus pentoxide is P4O10 and its atomicity is 14 (x=14). In P4O10, each P forms 5 bonds with neighboring atoms, this means that each P shared 5 electron paired and as their are 4 P atoms, hence value of y=20.

a) y  x = 6 20-14=6  a is correct b) 2x=y+8 2(14)=20+8   28=28  b is correct c) 10x-7y=0 10(14)-7(20)=0 140-140=0  c is correct

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