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Q.

Auto-ionization of liqNH3  is 2NH3NH4++NH2  with KNH3=(NH4+)(NH2)=1030 at500C  Number of amine ions (NH2)  present per mm3 of pure liquid NH3 is

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a

100

b

200

c

602

d

301

answer is A.

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Detailed Solution

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(A)  2NH3NH4++NH2
 [NH4+]=[NH2]=KNH3=1015M
1dm3 of solution contain 1015 moles=6.023×1023×1015  molecules of  NH2Θ
1mm3 of solution contain  6.023×1023×1015×106=602

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