Q.

Autoionisation of liquid NH3 occurs as
2NH3NH4++NH2 with KNH3=NH4+NH2=1030 at 50C
Number of amide ions, NH2 present per mm3 of pure liquid NH3 is

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a

100

b

200

c

602

d

300

answer is A.

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Detailed Solution

NH2=NH4+=KNH3=1015M=1015molL1 1015molL1=1015mol1000cm3=1015mol106mm3 =1015×6.02×1023106NH2ion /mm3=602

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